Pyrophosphoric acid, also known under the name
diphosphoric acid, is colorless, odorless,
hygroscopic and is soluble in
water,
diethyl ether, and
ethyl alcohol. The anhydrous acid has two different forms, which melt at 54.3°C and 71.5°C. It is best prepared by ion exchange from sodium pyrophosphate or by reacting hydrogen sulfide with lead pyrophosphate. When phosphoric acid is
dehydrated pyrophosphoric acid is produced as one of the products. When molten pyrophosphoric acid rapidly forms an equilibrium mixture of phosphoric acid, pyrophosphoric acid and polyphosphoric acids. The percentage by weight of pyrophosphoric acid is around 40
nd it is difficult to recrystallise from the melt. In aqueous solution pyrophosphoric acid like all polyphosphoric acids hydrolyses and eventually an equilibrium is established between phosphoric acid pyrophosphoric acid and polyphosphoric acids. When highly diluted an aqueous solution of pyrophosphoric acid contains only phosphoric acid.